The azimuthal quantum number determines shape of orbitals and can uniquely identify a subshell if given with a principal quantum number.
| subshell shape | |
|---|---|
| 0 | s |
| 1 | p |
| 2 | d |
| 3 | f |
Let be the energy level of the valence shell electron. For any electron in this atom, .
The number of orbitals in a certain subshell (a certain ) can be obtained from .